ELECTROCHEMICAL INVESTIGATION OF METAL CARBONYL-ISOCYANIDE COMPLEX CATIONS

被引：9

作者：

GRANT, ME

ALEXANDER, JJ

机构：

[1] Department of Chemistry, University of Cincinnati, Cincinnati

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1979年 / 9卷 / 04期

关键词：

D O I：

10.1080/00958977908073825

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polarogiaphic measurements on the cations [formula omitted] show an increasingly anodic one-electron reduction wave as CO is successively substituted by L. The effect is greater for L = CNCH3 than for L = PPh3. The reduced species then either lose L and dimerize (giving rise to a second reduction wave) or decompose. Heretofore unreported Mossbauer parameters for the isocyanide complexes are given and correlated with the polarographic results. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：205 / 210

页数：6

共 35 条

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