SYNTHESES OF CYCLOPENTANOLS BY A SILICON-INDUCED CASCADE REACTION

被引：39

作者：

FISCHER, MR ^{[1
]}

KIRSCHNING, A ^{[1
]}

MICHEL, T ^{[1
]}

SCHAUMANN, E ^{[1
]}

机构：

[1] UNIV CLAUSTHAL ZELLERFELD,INST ORGAN CHEM,D-38678 CLAUSTHAL ZELLERF,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 02期

关键词：

D O I：

10.1002/anie.199402171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Through the rare [4 + 1] construction strategy, the cyclopentanols 1 are accessible by a sequence of epoxide ring opening, silyl migration, and tosylate substitution. Optically active and annelated cyclopentanols can also be prepared by this route. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：217 / 218

页数：2

共 29 条

[1]

[Anonymous], 1993, ANGEW CHEM, DOI 10.1002/ange.19931050204

[2] NOVEL (4 + 1) FRAGMENT COMBINATION APPROACH TO CHIRAL CYCLOPENTANOIDS FROM TARTARIC ACID [J].

BARRIERE, F ;

BARRIERE, JC ;

BARTON, DHR ;

CLEOPHAX, J ;

GATEAUOLESKER, A ;

GERO, SD ;

TADJ, F .

TETRAHEDRON LETTERS, 1985, 26 (26) :3121-3124

[3]

Bartholeme P., 1984, Satellite Communications, Developments, Applications and Future Prospects. Proceedings of the 1984 International Conference, P1

[4]

CURRAN DP, 1988, SYNTHESIS-STUTTGART, V417, P489

[5]

Giese B., 1986, RADICALS ORGANIC SYN

[6] VINYLCYCLOPROPANE REARRANGEMENTS [J].

GOLDSCHMIDT, Z ;

CRAMMER, B .

CHEMICAL SOCIETY REVIEWS, 1988, 17 (03) :229-267

[7] VERSATILE 3-CARBON ANNELATION - SYNTHESIS OF CYCLOPENTANONES AND CYCLOPENTANONE DERIVATIVES FROM OLEFINS [J].

GREENE, AE ;

DEPRES, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (14) :4003-4005

[8] AN APPROACH TO THE BAKKANES - A SHORT, STEREOCONTROLLED TOTAL SYNTHESIS OF (+/-)-BAKKENOLIDE-A [J].

GREENE, AE ;

DEPRES, JP ;

COELHO, F ;

BROCKSOM, TJ .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (20) :3943-3945

[9] CYCLOPENTENONE DERIVATIVES .6. 4-OXO-2-CYCLOPENTENYL ACETATE - A SYNTHETIC INTERMEDIATE [J].

HARRE, M ;

RADDATZ, P ;

WALENTA, R ;

WINTERFELDT, E .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (07) :480-492

[10]

Harre M., 1982, ANGEW CHEM, V94, P496

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