CHIRAL ORGANOMETALLIC NADH MIMICS - PREPARATION OF HOMOCHIRAL (R)-(-)-[(ETA-5-C5H5)FE(CO)(PPH2(O-(L)-MENTHYL))]-1-METHYL-1,4-DIHYDRONICOTINOYL AND ASYMMETRIC REDUCTION OF ETHYL BENZOYLFORMATE

被引:23
作者
DAVIES, SG
SKERLJ, RT
WHITTAKER, M
机构
[1] The Dyson Perrins Laboratory, Oxford, OX1 3QY, South Parks Road
关键词
D O I
10.1016/S0040-4039(00)94735-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The homochiral complex (R)-(-)-[(η5-C5H5)Fe(CO)(PPh2(O-(l)-menthyl))]-1-methyl-1,4-dihydronicotinoyl reduces ethyl benzoylformate to ethyl mandelate in 52% enantiomeric excess. © 1990.
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页码:3213 / 3216
页数:4
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