The metal-centred radical [(eta-5-C5H5)Cr(CO)3]. abstracts the halogen atoms from a number of alkyl, allyl and benzyl halides to form the halochromium compounds [(eta-5-C5H5)Cr(CO)3X] (X = Br, 1) and the corresponding carbon-centred radicals; the latter subsequently undergo a wide variety of coupling, atom abstraction and atom donation reactions.
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[1]
Alfassi Z. B., 1988, CHEM KINETICS SMALL, V1, P129