ATOM TRANSFER-REACTIONS INVOLVING THE METAL-CENTERED RADICAL [(ETA-5-C5H5)CR(CO)3]

被引：16

作者：

GOULIN, CA ^{[1
]}

HUBER, TA ^{[1
]}

NELSON, JM ^{[1
]}

MACARTNEY, DH ^{[1
]}

BAIRD, MC ^{[1
]}

机构：

[1] QUEENS UNIV,DEPT CHEM,KINGSTON K7L 3N6,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 12期

关键词：

D O I：

10.1039/c39910000798

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The metal-centred radical [(eta-5-C5H5)Cr(CO)3]. abstracts the halogen atoms from a number of alkyl, allyl and benzyl halides to form the halochromium compounds [(eta-5-C5H5)Cr(CO)3X] (X = Br, 1) and the corresponding carbon-centred radicals; the latter subsequently undergo a wide variety of coupling, atom abstraction and atom donation reactions.

引用

页码：798 / 799

页数：2

共 9 条

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