ATOM TRANSFER-REACTIONS INVOLVING THE METAL-CENTERED RADICAL [(ETA-5-C5H5)CR(CO)3]

被引:16
作者
GOULIN, CA [1 ]
HUBER, TA [1 ]
NELSON, JM [1 ]
MACARTNEY, DH [1 ]
BAIRD, MC [1 ]
机构
[1] QUEENS UNIV,DEPT CHEM,KINGSTON K7L 3N6,ONTARIO,CANADA
关键词
D O I
10.1039/c39910000798
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The metal-centred radical [(eta-5-C5H5)Cr(CO)3]. abstracts the halogen atoms from a number of alkyl, allyl and benzyl halides to form the halochromium compounds [(eta-5-C5H5)Cr(CO)3X] (X = Br, 1) and the corresponding carbon-centred radicals; the latter subsequently undergo a wide variety of coupling, atom abstraction and atom donation reactions.
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页码:798 / 799
页数:2
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