DIHYDROBISTRIPHENYLPHOSPHINE AND TRIS(TRIPHENYLPHOSPHINE)RHODIUM(III) CARBOXYLATE COMPLEXES

被引：7

作者：

CARLTON, L

BELCIUG, MP

PATTRICK, G

机构：

[1] Centre for Molecular Design, Department of Chemistry, University of the Witwatersrand, Johannesburg

来源：

POLYHEDRON | 1992年 / 11卷 / 12期

关键词：

D O I：

10.1016/S0277-5387(00)83143-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [Rh(H)2(O2CArN)(PPh3)2] (O2CArN = pyridine-2-carboxylate, 6-methylpyridine-2-carboxylate, pyrazine-2-carboxylate, quinoline-2-carboxylate, isoquinoline-1-carboxylate and quinoxaline-2-carboxylate) were formed in high yield by the reaction of [RhH(PPh3)4] with the carboxylic acids NArCO2H; their properties are compared with those of [Rh(H)2(O2CR)(PPh3)3] and [Rh(H)2(O2CR)(PPh3)2(py)] (O2CR = acetate, thiophene-2-carboxylate; py = pyridine).

引用

页码：1501 / 1506

页数：6

共 9 条

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