TOTAL SYNTHESIS OF THE MYCOTOXIN (-)-ZEARALENONE BASED ON MACROCYCLIZATION USING A CINNAMYL RADICAL INTERMEDIATE

被引：25

作者：

HITCHCOCK, SA ^{[1
]}

PATTENDEN, G ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 11期

关键词：

D O I：

10.1039/p19920001323

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A concise synthesis of optically active (-)-zearalenone, which uses a novel 14-endo-trig macrocyclisation from a cinnamyl radical intermediate onto an alpha, beta-enone electrophore as a key feature, is described.

引用

页码：1323 / 1328

页数：6

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