EXPERIMENTAL-DETERMINATION OF THE LONG-TIME BEHAVIOR IN REVERSIBLE BINARY CHEMICAL-REACTIONS

被引：82

作者：

HUPPERT, D

GOLDBERG, SY

MASAD, A

AGMON, N

机构：

[1] HEBREW UNIV JERUSALEM,FRITZ HABER RES CTR,IL-91904 JERUSALEM,ISRAEL

[2] HEBREW UNIV JERUSALEM,DEPT PHYS CHEM,IL-91904 JERUSALEM,ISRAEL

来源：

PHYSICAL REVIEW LETTERS | 1992年 / 68卷 / 26期

关键词：

D O I：

10.1103/PhysRevLett.68.3932

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

A new asymptotic behavior of reversible pseudo first-order binary chemical reactions is revealed by time-resolved fluorescence measurements of excited-state proton transfer. The asymptotic behavior is a power-law rather than the exponential decay expected from the chemical rate equations. Unlike the conclusion from mean-field approximations, the power seems to increase with concentration.

引用

收藏

页码：3932 / 3935

页数：4

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