SIMPLE CYCLOPLATINATION OF TRIPHENYLPHOSPHINE

被引：12

作者：

SCHEFFKNECHT, C

RHOMBERG, A

MULLER, EP

PERINGER, P

机构：

[1] UNIV INNSBRUCK, INST ORGAN & PHARMAZEUT CHEM, A-6020 INNSBRUCK, AUSTRIA

[2] UNIV INNSBRUCK, INST ANORGAN & ANALYT CHEM, A-6020 INNSBRUCK, AUSTRIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 463卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83425-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [PtCl(PPh(3))(3)]Cl with AgO3SCF3 in CHCl3/MeOH at ambient temperature gives [Pt(PPh(2)C(6)H(4))(PPh(3))(2)]O3SCF3 (3) in quantitative yield within a few minutes. The cyclometallated complex 3 has been characterized by H-1, C-13, P-31 and Pt-195 NMR spectroscopies. Complete H-1 and C-13 assignments have been made by use of various one- and two-dimensional NMR techniques.

引用

页码：245 / 248

页数：4

共 26 条

[1] REACTIONS OF DICHLORO(DIPHOSPHINE)PLATINUM(II) COMPLEXES WITH TERTIARY PHOSPHINES - P-31(H-1) NMR-STUDIES OF [PTCL(PR3)(PP)]+ AND [PT(PR3)2(PP)]2+ (PP=1,2-BIS(DIPHENYLPHOSPHINO)ETHANE (DPPE), 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE (DMPE), OR BIS(DIPHENYLPHOSPHINO)METHANE (DPPM))
ANDERSON, GK
LUMETTA, GJ
[J]. INORGANIC CHEMISTRY, 1987, 26 (10) : 1518 - 1524
[2] H-1 AND C-13 ASSIGNMENTS FROM SENSITIVITY-ENHANCED DETECTION OF HETERONUCLEAR MULTIPLE-BOND CONNECTIVITY BY 2D MULTIPLE QUANTUM NMR
BAX, A
SUMMERS, MF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (08) : 2093 - 2094
[3] SENSITIVITY-ENHANCED TWO-DIMENSIONAL HETERONUCLEAR SHIFT CORRELATION NMR-SPECTROSCOPY
BAX, A
SUBRAMANIAN, S
[J]. JOURNAL OF MAGNETIC RESONANCE, 1986, 67 (03) : 565 - 569
[4] BENDALL MR, 1983, J MAGN RESON, V53, P272, DOI 10.1016/0022-2364(83)90032-X
[5] RATIONAL SYNTHESIS OF DINUCLEAR COMPLEXES OF PLATINUM(I) AND PLATINUM(II) CONTAINING BRIDGING ORTHO-METALATED TRIPHENYLPHOSPHINE LIGANDS FROM THE MONOMERIC BIS(CHELATE) PLATINUM(II) COMPLEX PT(ORTHO-C6H4PPH2)2
BENNETT, MA
BERRY, DE
BHARGAVA, SK
DITZEL, EJ
ROBERTSON, GB
WILLIS, AC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) : 1613 - 1615
[6] BLAKE DM, 1969, J CHEM SOC CHEM COMM, P483
[7] INTERMOLECULAR ACTIVATION OF C-D BONDS IN BENZENE-D6 BY TRANS-NEOPENTYL(TRIFLUOROMETHANESULFONATO)BIS(TRIMETHYL-PHOSPHINE)PLATINUM(II)
BRAINARD, RL
NUTT, WR
LEE, TR
WHITESIDES, GM
[J]. ORGANOMETALLICS, 1988, 7 (11) : 2379 - 2386
[8] BRUNE HA, 1986, Z NATURFORSCH B, V41, P211
[9] SYNTHETIC AND X-RAY STRUCTURAL STUDIES OF COMPLEXES FORMED BY METALATION OF TRI(1-PYRAZOLYL)METHANE BY DIMETHYLPLATINUM(II)
CANTY, AJ
MINCHIN, NJ
PATRICK, JM
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (07): : 1253 - 1259
[10] TRANSITION METAL-CARBON BONDS .29. SOME INTERNAL METALLATION REACTIONS OF TERTIARY PHOSPHINE LIGANDS WITH BULKY SUBSTITUENTS
CHENEY, AJ
MANN, BE
SHAW, BL
SLADE, RM
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (23): : 3833 - &

← 1 2 3 →