THERMAL-DECOMPOSITION OF ALLYLIC SULFINIC ACIDS - A STUDY OF A RETRO-ENE TRANSITION-STATE

被引：6

作者：

HISCOCK, SD

ISAACS, NS

KING, MD

YOUNG, DJ

机构：

[1] UNIV READING, DEPT CHEM, READING RG6 2AD, BERKS, ENGLAND

[2] GRIFFITH UNIV, FAC SCI & TECHNOL, BRISBANE, QLD 4111, AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期

关键词：

D O I：

10.1039/c39940001381

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.

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页码：1381 / 1382

页数：2

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