6 MEMBERED RING-OPENING OF ISOPROPYLIDENE MALONATE DERIVATIVES - SYNTHESIS OF ALPHA,BETA-UNSATURATED THIOARYL AND SELENOARYL CARBOXYLIC ESTERS

被引：16

作者：

BAO, WL

ZHANG, YM

机构：

[1] Department of Chemistry, Hangzhou University

来源：

SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 02期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1080/00397919508010800

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Six membered rings of isopropylidene malonate derivatives were opened by aryl thiolate anions and aryl selenolate anions which were produced through reductive cleavage of diaryl disulfides and diaryl diselenides with SmI2, and the substituted propenoic acid selenoaryl and thioaryl esters were synthesized.

引用

页码：143 / 148

页数：6

共 7 条

[1]

BAO WL, IN PRESS SYNTH COMMU

[2]

FUKUZAWA SI, 1990, HETEROATOM CHEM, P491

[3] CONJUGATE ADDITION OF GRIGNARD-REAGENTS TO SUBSTITUTED ISOPROPYLIDENE METHYLENEMALONATES [J].