MICROBIOLOGICAL OXIDATION OF LONG-CHAIN ALIPHATIC COMPOUNDS .3. 1-HALOGENOALKANES 1-CYANOHEXADECANE AND 1-ALKOXYALKANES

被引:7
作者
JONES, DF
HOWE, R
机构
[1] Imperial Chemical Industries Limited, Pharmaceutical Division, Macclesfield, Cheshire
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 22期
关键词
D O I
10.1039/j39680002816
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In a medium containing glucose, the yeast Torulopsis gropengiesseri effects the following transformations: (a) long-chain 1-halogenoalkanes to αω-alkanedioic acids; (b) 1-cyanohexadecane to the cyanohydrin derivative of 16-oxohexadecanoic acid; (c) long-chain 1-methoxyalkanes and 1-ethoxyalkanes to ω-hydroxyalkanoic acids; (d) long-chain 1-propoxyalkanes to ω- and ω-1-hydroxyalkoxyalkanoic acids. The transformation products separate from the culture medium as glycolipids. Metabolic pathways which account for these transformations are proposed.
引用
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页码:2816 / &
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