2ND DIMENSION IN METAL VAPOR CHEMISTRY - NEW GENERAL-SYNTHESIS FOR METAL ALKYLS

被引:41
作者
JUHLKE, TJ [1 ]
BRAUN, RW [1 ]
BIERSCHENK, TR [1 ]
LAGOW, RJ [1 ]
机构
[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712
关键词
D O I
10.1021/ja00506a016
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new synthesis has been developed for preparation of M(R)n metal alkyls and other similar compounds. The reactive free radicals CH3., CF3., and SiF3. have been cocondensed with metals on a cold finger at -196 °C and oxidize the metals to the compounds Hg(CF3)2, Te(CF3)2, Te2(CF3)2, Bi(CF3)3, Hg(CH3)2, Cd(CH3)2, Bi(CF3)3, Sn(CH3)4), Ge(CH3)4, Hg(SiF3)2. © 1979, American Chemical Society. All rights reserved.
引用
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页码:3229 / 3231
页数:3
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