2ND DIMENSION IN METAL VAPOR CHEMISTRY - NEW GENERAL-SYNTHESIS FOR METAL ALKYLS

被引：41

作者：

JUHLKE, TJ ^{[1
]}

BRAUN, RW ^{[1
]}

BIERSCHENK, TR ^{[1
]}

LAGOW, RJ ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 12期

关键词：

D O I：

10.1021/ja00506a016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new synthesis has been developed for preparation of M(R)n metal alkyls and other similar compounds. The reactive free radicals CH3., CF3., and SiF3. have been cocondensed with metals on a cold finger at -196 °C and oxidize the metals to the compounds Hg(CF3)2, Te(CF3)2, Te2(CF3)2, Bi(CF3)3, Hg(CH3)2, Cd(CH3)2, Bi(CF3)3, Sn(CH3)4), Ge(CH3)4, Hg(SiF3)2. © 1979, American Chemical Society. All rights reserved.

引用

页码：3229 / 3231

页数：3

共 18 条

[1] JUHLKE T, UNPUBLISHED
[2] ORGANIC-CHEMISTRY OF METAL VAPORS
KLABUNDE, KJ
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1975, 8 (12) : 393 - 399
[3] REACTIONS OF METAL ATOMS WITH FLUOROCARBONS
KLABUNDE, KJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (05): : 287 - 292
[4] NEW GENERAL SYNTHESIS FOR TRIFLUOROMETHYL ORGANOMETALLIC COMPOUNDS
LAGOW, RJ
GERCHMAN, LL
JACOB, RA
MORRISON, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (03) : 518 - 522
[5] LAGOW RJ, 1973, J CHEM SOC CHEM COMM, P104
[6] LAGOW RJ, J CHEM SOC CHEM COMM
[7] LAGOW RJ, ADV INORG CHEM RADIO
[8] LAGOW RJ, INORG CHEM
[9] LAGOW RJ, 1975, INORG CHEM, V14, P3128
[10] LAGOW RJ, 1977, INORG CHEM, V16, P1823

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