REVERSIBLE THERMAL AND PHOTOCHEMICAL INTERCONVERSION BETWEEN CIS AND TRANS ISOMERS OF THE SILYLENE-BRIDGED DIIRON COMPLEX CP'2FE2(CO)3(MU-SIHTOL) (CP'=ETA-C5ME5, TOL=PARA-CH3C6H4)

被引：25

作者：

KAWANO, Y ^{[1
]}

TOBITA, H ^{[1
]}

OGINO, H ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,AOBA KU,SENDAI,MIYAGI 980,JAPAN

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 02期

关键词：

D O I：

10.1021/om00038a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Isomerization between cis-Cp'2Fe2(CO)3(mu-SiHTol) (cis-1; Cp' = eta-C5Me5, Tol = p-CH3C6H4) and trans-1 was found to occur both thermally and photochemically. The composition in the thermal equilibrium state (cis-1:trans-1 = 2:98 in cyclohexane-d 12) is considerably different from that in the photostationary state (cis-1:trans-1 = 70:30).

引用

页码：499 / 500

页数：2

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