MODEL REACTIONS TO ANCHOR MOLYBDENUM AND VANADIUM-OXIDES ON SILICA-OXYGEN SURFACES

被引：37

作者：

GOSINK, HJ ^{[1
]}

ROESKY, HW ^{[1
]}

NOLTEMEYER, M ^{[1
]}

SCHMIDT, HG ^{[1
]}

FREIREERDBRUGGER, C ^{[1
]}

SHELDRICK, GM ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 02期

关键词：

MOLYBDENUM(VI) COMPOUND; SILOXANES; VANADIUM(V) COMPOUND;

D O I：

10.1002/cber.19931260202

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The eight- and twelve-membered ring compounds [(tBu)2-Si(O)2MoO2]2 (1) and [(tBu)2Si(O)2V(O)Cl]3 (2) have been prepared by the reaction of di-tert-butylsilanediol or its dilithium salt with MoO2Br2 Or VOCl3, respectively. Single crystal X-ray structure analyses of 1 . 2 py and 2 have been performed. Crystals of 1 . 2 py contain two molecules of 1 . 2 py and four additional molecules of pyridine in the unit cell.

引用

页码：279 / 283

页数：5

共 18 条

[1] SYNTHETIC APPROACH TO THE MONONUCLEAR ACTIVE-SITES OF MOLYBDOENZYMES - CATALYTIC OXYGEN ATOM TRANSFER-REACTIONS BY OXOMOLYBDENUM(IV,VI) COMPLEXES WITH SATURATION KINETICS AND WITHOUT MOLYBDENUM(V) DIMER FORMATION [J].

BERG, JM ;

HOLM, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (10) :3035-3036

[2] OLEFIN POLYMERIZATION BY VANADIUM-CONTAINING POLYHEDRAL OLIGOMETALLASILSESQUIOXANES [J].

FEHER, FJ ;

WALZER, JF ;

BLANSKI, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (09) :3618-3619

[3] SYNTHESIS AND CHARACTERIZATION OF VANADIUM-CONTAINING SILSESQUIOXANES [J].

FEHER, FJ ;

WALZER, JF .

INORGANIC CHEMISTRY, 1991, 30 (08) :1689-1694

[4] SILSESQUIOXANES AS MODELS FOR SILICA SURFACES [J].

FEHER, FJ ;

NEWMAN, DA ;

WALZER, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (05) :1741-1748

[5] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[6] SYNTHESIS AND STRUCTURE OF 8-MEMBERED TITANIUM AND ZIRCONIUM CONTAINING SILOXANE RINGS [J].

HAOUDIMAZZAH, A ;

MAZZAH, A ;

SCHMIDT, HG ;

NOLTEMEYER, M ;

ROESKY, HW .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (05) :587-592

[7] DIOXOMOLYBDENUM(VI)-SUBSTITUTED 2,6-PYRIDINEDIMETHANOL COMPLEXES - NEW 5-COORDINATE SPECIES [J].

HAWKINS, JM ;

DEWAN, JC ;

SHARPLESS, KB .

INORGANIC CHEMISTRY, 1986, 25 (09) :1501-1503

[8] THE CRYSTAL AND MOLECULAR-STRUCTURE OF HEXADECAPHENYLOCTASILOXYSPIRO(9,9)TITANATE(IV) [J].

HURSTHOUSE, MB ;

HOSSAIN, A .

POLYHEDRON, 1984, 3 (01) :95-97

[9]

LEONOV VN, 1988, IAN SSSR KH, V9, P1976

[10] OXOVANADIUM ALKOXIDES - STRUCTURE, REACTIVITY, AND V-51 NMR CHARACTERISTICS - CRYSTAL AND MOLECULAR-STRUCTURES OF VO(OCH2CH2CL)3 AND VOCL2(THF)2H2O [J].

PRIEBSCH, W ;

REHDER, D .

INORGANIC CHEMISTRY, 1990, 29 (16) :3013-3019

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