CATALYTIC ASYMMETRIC ALLYLATION REACTIONS .3. EXTENSION TO METHALLYLSTANNANE, COMPARISON OF PROCEDURES, AND OBSERVATION OF A NONLINEAR EFFECT

被引：156

作者：

KECK, GE

KRISHNAMURTY, D

GRIER, MC

机构：

[1] Department of Chemistry, University of Utah, Salt Lake City

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 24期

关键词：

D O I：

10.1021/jo00076a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantioselective additions of methallylstannanes to representative aldehydes with four chiral Lewis acid systems afford ee's of 84-99% using 10 mol % of catalyst. In one case, use of (R)-BINOL of 50% ee gave product with 88% ee.

引用

页码：6543 / 6544

页数：2

共 12 条

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