PHENOL-ASSISTED PHOTOLYTIC AND RADIOLYTIC RADICAL-CATION FORMATION OF A STERICALLY HINDERED TERTIARY AMINE

被引：5

作者：

BREDE, O

ORTHNER, H

HERMANN, R

机构：

[1] Max Planck Society, Group for Time-Resolved Spectroscopy, the University of Leipzig, D-04303 Leipzig

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 229卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(94)01076-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

With 266 nm laser pulses a compound whose molecular structure incorporates a sterically hindered phenol group and two sterically hindered N-methyl piperidine groups was ionized in a two-photon process. From the intermediate phenol radical cation the change is transferred to the amine moiety, generating tertiary amine radical cations. This phenomenon is likely to proceed via an intramolecular charge transfer through space.

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页码：571 / 576

页数：6

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