ENTHALPY OF MIXING OF BROMOBENZENE WITH N-ALKANES, WITH CYCLOHEXANE, AND WITH BENZENE

被引：19

作者：

WILHELM, E ^{[1
]}

INGLESE, A ^{[1
]}

GROLIER, JPE ^{[1
]}

KEHIAIAN, HV ^{[1
]}

机构：

[1] CNRS,CTR RECH MICROCALORIMETRIE & THERMOCHIM,F-13003 MARSEILLE,FRANCE

来源：

THERMOCHIMICA ACTA | 1979年 / 31卷 / 01期

关键词：

D O I：

10.1016/0040-6031(79)80011-8

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A dynamic flow microcalorimeter of the Picker design was used to measure enthalpies of mixing at 298.15 K and atmospheric pressure of the six binary systems bromobenzene + n-hexane, + n-heptane, + n-nonane, + n-tetradecane, + cyclohexane, and + benzene. Within the homologous series of n-alkane systems, the interaction parameter, h12, calculated from rigid-lattice group contribution theory, decreases weakly with increasing chain length of the alkane. This behavior is quite analogous to that observed with chloro-derivatives of benzene + n-alkane. © 1979.

引用

页码：85 / 92

页数：8

共 21 条

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