3RD-ORDER NLO PROPERTIES OF METAL-COMPLEXES CONTAINING DELOCALIZED NITROGEN DONOR LIGANDS

被引：5

作者：

DHINDSA, AS ^{[1
]}

UNDERHILL, AE ^{[1
]}

OLIVER, S ^{[1
]}

KERSHAW, S ^{[1
]}

机构：

[1] BRITISH TELECOMMUN PLC,RES LABS,IPSWICH,SUFFOLK,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 02期

关键词：

D O I：

10.1039/jm9950500261

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Complexes of 3,4-toluenediamine, [M(tdi)(2)] where M=Ni, Pd or Pt, and 3,4-benzophenonediamine, [Ni(bpdi)(2)], have been synthesized and the value of chi((3)) has been determined in DMSO at 1064 nm by the retroreflection DFWM technique. A value for chi((3)) Of 10.3 X 10(-13) esu was observed for [Ni(bpdi)(2)] with a ratio of chi(xxxx)(3)/chi(xyyx)((3)) of 3, suggesting a non-linear process that is predominantly electronic.

引用

页码：261 / 264

页数：4

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