FLUORESCENCE LIFETIMES IN THE BIPHENYL-TETRACYANOBENZENE CRYSTAL DOPED WITH TCNQ

被引:5
作者
AGOSTINI, G [1 ]
GIACOMETTI, G [1 ]
TOFFOLETTI, A [1 ]
PASIMENI, L [1 ]
机构
[1] UNIV MESSINA,DIPARTIMENTO CHIM INORGAN & STRUTTURA MOLEC,I-98100 MESSINA,ITALY
来源
NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS | 1990年 / 12卷 / 02期
关键词
Photoluminescence;
D O I
10.1007/BF02450458
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Transient optical emission spectra of biphenyl-1,2,4,5-tetracyanobenzene crystal doped with TCNQ have been investigated in the (77÷300) K temperature range. Host prompt fluorescence lifetimes have been measured by cross-correlation phase fluorometry. The decay signal is fitted by a biexponential function whose coefficients are strongly dependent on temperature. A thermal activation energy of 300 cm-1 for the diffusion of singlet exciton has been determined. © 1990 Società Italiana di Fisica.
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页码:233 / 243
页数:11
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