ENUMERATION OF INTERNAL-ROTATION REACTIONS AND THEIR REACTION GRAPHS

被引：67

作者：

BALASUBRAMANIAN, K

机构：

[1] Department of Chemistry, The Johns Hopkins University, Baltimore, 21218, Maryland

来源：

THEORETICA CHIMICA ACTA | 1979年 / 53卷 / 02期

关键词：

Atropisomerism; Borel fields; NMR spectra; Optical activity; spontaneous generation of ∼; Rotation reactions;

D O I：

10.1007/BF00548826

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Threefold and twofold internal rotation reactions and their reaction graphs are enumerated using the generalized wreath product method developed by the author in an earlier paper. The correspondence between reaction directed graphs (digraphs) and finite topologies on isomers is established. It is shown that the reaction digraphs can be represented by Borel fields. Atropisomerism in polyphenyl compounds is discussed. Applications to spontaneous generation of optical activity and NMR spectroscopy are considered. Borel fields are enumerated by bumping squares of the upper rows of Young diagrams starting from the Young diagram containing just one row. © 1979 Springer-Verlag.

引用

页码：129 / 146

页数：18

共 26 条

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