CRYSTAL AND MOLECULAR-STRUCTURE OF CHLORO(ETHYL L-CYSTEINATO-N,S) DIMETHYLTIN (IV)

被引：22

作者：

DOMAZETIS, G ^{[1
]}

MACKAY, MF ^{[1
]}

机构：

[1] LA TROBE UNIV,DEPT CHEM,BUNDOORA,VIC 3083,AUSTRALIA

来源：

JOURNAL OF CRYSTAL AND MOLECULAR STRUCTURE | 1979年 / 9卷 / 02期

关键词：

D O I：

10.1007/BF01387558

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Orthorhombic crystals of the title compound, C7H16ClNO2SSn, belong to space group P212121, with a = 6.658(5), b = 10.974(3), c = 17.144(5) Å, and Z = 4. The diffractometer data, measured with Cu Kα radiation, has been refined to an R index of 0.053 for 1110 observed terms. The geometry about the Sn atom in the monomeric complex units is distorted trigonal bipyramidal; the N and Cl atoms are in the apical positions, and the Sn lies at 0.107(1) Å from the equatorial plane. The Sn-Cl, Sn-S, and Sn-N bonds have lengths 2.523(4), 2.413(3), and 2.434(12) respectively, and the angle N-Sn is 166.9(3) °. © 1980 Plenum Publishing Corporation.

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页码：57 / 65

页数：9

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