DEHYDROGENATIVE COUPLING OF SUBSTITUTED PHENYLSILANES - SYNTHESIS OF POLY[((TRIFLUOROMETHYL)PHENYL)SILANES]

被引：54

作者：

BANOVETZ, JP ^{[1
]}

SUZUKI, H ^{[1
]}

WAYMOUTH, RM ^{[1
]}

机构：

[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 11期

关键词：

D O I：

10.1021/om00035a070

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dehydrogenative coupling of substituted phenylsilanes XC6H4SiH3 (X = p-CF3 (2a), m-CF3 (2b), o-CF3 (2c), p-CH3 (3a), m-CH3 (3b), o-CH3 (3c), H (4)) was carried out with Cp2Zr(Si(SiMe3)3)Me (1b). The molecular weight of the polymers produced ranged from 1000 to 3000 (vs polystyrene) with PDI = 1.5-2.4. Relative rates of polymerization for the substituted phenylsilanes were deduced by copolymerization reactions with phenylsilane.

引用

页码：4700 / 4703

页数：4

共 54 条

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