INTRAMOLECULAR CARBOCYCLIZATION AND HETEROCYCLIZATION INDUCED BY SYSTEMATIC DEMETALATION OF (ETA(3)-BUTADIENYL) PALLADIUM COMPLEXES

被引：65

作者：

PFEFFER, M ^{[1
]}

SUTTER, JP ^{[1
]}

DECIAN, A ^{[1
]}

FISCHER, J ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,CRISTALLOCHIM & CHIM STRUCT LAB,CNRS,URA 424,F-67070 STRASBOURG,FRANCE

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 04期

关键词：

D O I：

10.1021/om00028a034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The treatment of organopalladium complexes containing a polysubstituted butadienyl group eta3-bound to Pd, [GRAPHICS] with PPh3 in methanol, led to palladium-free compounds in several instances. These depalladation reactions afforded selectively carbo- and heterocyclic products whose nature was only dependent upon the substituents of the butadienyl fragment.

引用

页码：1167 / 1173

页数：7

共 30 条

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