HETERO-DIELS-ALDER REACTION INVOLVING (E)-3-(TERT-BUTYLDIMETHYLSILOXY)-1-(2',3',4',6'-TETRA-O-ACETYL-BETA-D-GLUCOPYRANOSYLOXY)BUTA-1,3-DIENE AND P-NITROBENZALDEHYDE

被引：25

作者：

LOWE, RF ^{[1
]}

STOODLEY, RJ ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(00)73430-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title reaction, when carried out in carbon tetrachloride in the presence of a catalytic amount of Eu(fod)(3), leads mainly to the cis-cycloadduct 6a; the product undergoes isomerisation to its epimer 7a in the presence of the catalyst in dichloromethane.

引用

页码：6351 / 6354

页数：4

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