IR-SPECTRA OF CO AND NO ADSORBED ON C-60

被引:26
作者
FASTOW, M [1 ]
KOZIROVSKI, Y [1 ]
FOLMAN, M [1 ]
HEIDBERG, J [1 ]
机构
[1] UNIV HANOVER,INST PHYS CHEM & ELEKTROCHEM,W-3000 HANNOVER,GERMANY
关键词
D O I
10.1021/j100194a008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
The adsorption of CO and NO on C60 is studied using the technique of IR spectroscopy. The IR spectra of CO show two absorption bands, which indicate the presence of two adsorption sites on the C60 surface. The IR spectra of NO show, in addition, a multiplicity in the two absorption bands, which indicates that NO is adsorbed in its dimer form on two sites. Large spectral shifts are observed on adsorption of both CO and NO on C60, demonstrating that the interaction of these gases with C60 is relatively strong.
引用
收藏
页码:6126 / 6128
页数:3
相关论文
共 2 条
[1]
C60 - BUCKMINSTERFULLERENE [J].
KROTO, HW ;
ALLAF, AW ;
BALM, SP .
CHEMICAL REVIEWS, 1991, 91 (06) :1213-1235
[2]
IR-SPECTRA OF SMALL MOLECULES ADSORBED ON CARBON-FILMS - ADSORPTION POTENTIALS AND SPECTRAL SHIFTS [J].
TSIDONI, E ;
KOZIROVSKI, Y ;
FOLMAN, M ;
HEIDBERG, J .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1987, 44 :89-98