PREDICTION OF ENVIRONMENTAL PARAMETERS BY ADSORBABILITY INDEX - WATER SOLUBILITIES OF HYDROPHOBIC ORGANIC POLLUTANTS

被引：7

作者：

OKOUCHI, S

SAEGUSA, H

NOJIMA, O

机构：

[1] Chemistry Laboratory, College of Engineering, Hosei University, Koganei, Tokyo

来源：

ENVIRONMENT INTERNATIONAL | 1992年 / 18卷 / 03期

关键词：

D O I：

10.1016/0160-4120(92)90108-G

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The adsorbability index proposed by Abe et al. to predict the activated carbon adsorption of organic compounds from aqueous solutions was found to be an effective parameter for predicting the water solubilities of 265 hydrophobic organic pollutants which were classified into 118 aliphatic compounds and 88 mono- and 59 polynuclear aromatic compounds; and, furthermore, for predicting the total molecular surface areas of these compounds.

引用

页码：249 / 261

页数：13

共 10 条

[1]

Abe, Tatsumoto, Hirashima, Prediction of activated carbon adsorption by adsorbability index (AI), Japan journal of water pollution research, 9, pp. 153-161, (1986)

[2]

Kishi, Nakamura, Hashimoto, Prediction of solubility of aromatic compounds in water by using total molecular surface area, NIPPON KAGAKU KAISHI, pp. 1615-1622, (1987)

[3]

Mackay, Mascarenhas, Shiu, Aqueous solubility of polychlorinated biphenyls, Chemosphere, 9, pp. 257-264, (1980)

[4]

Mackay, Shiu, A critical review of Henry's law constants for chemicals of environmental interest, Journal of Physical and Chemical Reference Data, 10, pp. 1175-1199, (1981)

[5]

Mallhot, Peters, Empirical relationships between the 1-octanol/water partition coefficient and nine physicochemical properties, Environmental Science & Technology, 22, pp. 1479-1488, (1988)

[6]

Nirmalakhandan, Speece, Prediction of aqueous solubility of organic chemicals based on molecular structure, Environ. Sci. Technol., 22, pp. 328-338, (1988)

[7]

Nirmalakhandan, Speece, QSAR model for predicting Henry's constant, Environ. Sci. Technol., 22, pp. 1349-1357, (1988)

[8]

Okouchi, Saegusa, Prediction of soil sorption coefficients of hydrophobic organic pollutants by adsorbability index, Bulletin of the Chemical Society of Japan, 62, pp. 922-924, (1989)

[9]

Pearlman, Yalkowsky, Banerjee, Water solubilities of polynuclear aromatic and heteroaromatic compounds, Journal of Physical and Chemical Reference Data, 13, (1984)

[10]

Yalkowsky, Valvani, Solubility and partitioning I: Solubility of nonelectrolysis in water, J. Pharm. Sci., 69, pp. 912-922, (1980)

← 1 →