NEW METALLOCENE COMPOUNDS OF ZIRCONIUM AND HAFNIUM SHOWING UNUSUAL ANSA-LIGAND COORDINATION - X-RAY CRYSTAL-STRUCTURES OF [((CH2)(5)C(ETA(5)-C5H4)(ETA(2)-C9H6))ZR(ETA(5)-C5H5)CL] AND [(ME(2)C(ETA(5)-C5H4)(ETA(3)-C13H8))ZR(ETA(5)-C5H5)CL]

被引：33

作者：

DIAMOND, GM

GREEN, MLH

MOUNTFORD, P

POPHAM, NA

CHERNEGA, AN

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

[2] CHEM CRYSTALLOG LAB,OXFORD OX1 3PD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 01期

关键词：

D O I：

10.1039/c39940000103

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new ansa-bridged compounds [{Me(2)C(eta(5)-C5H4)(eta(2)-C9H6)}M(eta(5)-C5H5)Cl], [{(CH2)(5)C(eta(5)-C5H4)(eta(2)-C9H6)}M(eta(5)-C5H5)Cl] (M = Zr, Hf) and[{[Me(2)C(eta(5)-C5H4)(eta(3)-C13H8))Zr(eta(5)-C5H5)Cl] show unusual modes of coordination of the indenyl or fluorenyl groups.

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页码：103 / 105

页数：3

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