THE NOVEL PHOTOCHEMICAL BEHAVIOR OF TRIPTYCENE-1,4-QUINONE

被引：9

作者：

FU, TY ^{[1
]}

GAMLIN, JN ^{[1
]}

OLOVSSON, G ^{[1
]}

SCHEFFER, JR ^{[1
]}

TROTTER, J ^{[1
]}

YOUNG, DT ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER,BC V6T 1Z1,CANADA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 12期

关键词：

D O I：

10.1016/0040-4039(95)00228-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Triptycene-1,4-quinone (1) reacts photochemically in solution to give different products depending on the solvent employed and on the presence or absence of oxygen. The structures of the photoproducts have been elucidated by spectroscopic methods, independent synthesis and single crystal X-ray diffractometry, and possible mechanistic pathways leading to their formation are presented and discussed. Unexpectedly, quinone 1 was found to be photochemically inert in the crystalline state. The X-ray crystal structure of 1 reveals the probable reason for this behavior.

引用

页码：2025 / 2028

页数：4

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