POLYANILINE COMPOUNDS .3. REACTION OF PHENYL-AND METHYLLITHIUM WITH N,N'-DIPHENYL-P-QUINONE DIIMINE

被引：52

作者：

HONZL, J

METALOVA, M

机构：

[1] Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, Prague

来源：

TETRAHEDRON | 1969年 / 25卷 / 17期

关键词：

D O I：

10.1016/S0040-4020(01)82897-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of N,N′-diphenyl-p-quinone diimine (I) with PhLi proceeds predominantly as 1,6-addition together with reduction. In an analogous reaction with MeLi, in addition to reduction 1,6- and 1,4-addition was found to take place probably together with 1,2-addition. The influence of metal salts on the reaction course was studied, and possible mechanisms are discussed. © 1969.

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页码：3641 / &

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共 35 条

[1] STUDIES ON THE MECHANISM OF CONJUGATE ADDITION .1. THE ADDITION OF GRIGNARD REAGENTS TO 2-CYCLOHEXENONE AND SOME OPEN CHAIN ANALOGS [J].

ALEXANDER, ER ;

CORAOR, GR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (06) :2721-2723

[2] Action of phenyhnagnesium bromide on anthraquinones. II [J].

Allen, CFH ;

Bell, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :2408-2412

[3] Action of Grignard reagents on certain pentacenequinones, 6,13-diphenylpentacene [J].

Allen, CFH ;

Bell, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 :1253-1260

[4] PROPERTIES AND REACTIONS OF FREE ALKYL RADICALS IN SOLUTION .5. A STUDY OF THE REACTIONS OF THE 2-CYANO-2-PROPYL RADICAL WITH QUINONES [J].

APARICIO, FJL ;

WATERS, WA .

JOURNAL OF THE CHEMICAL SOCIETY, 1952, (DEC) :4666-4674

[5] 1,6-ADDITION OF A GRIGNARD REAGENT TO ANTHRAQUINONE [J].

CAMERON, DW ;

MECKEL, W .

CHEMICAL COMMUNICATIONS, 1967, (13) :623-&

[6] THE PREPARATION OF 2,3-DIPHENYL-1,4-NAPHTHOQUINONE AND ITS REACTION WITH PHENYLMAGNESIUM BROMIDE AND PHENYLLITHIUM [J].

CRAWFORD, HM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (03) :1081-1084

[7] THE REACTION BETWEEN DUROQUINONE AND PHENYLLITHIUM [J].

CRAWFORD, HM ;

MCDONALD, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2681-2682

[8] THE REACTIONS OF PHENANTHRENEQUINONE AND 2,5-DI-TERT-BUTYL-1,4-BENZOQUINONE WITH PHENYLLITHIUM AND WITH PHENYLMAGNESIUM BROMIDE [J].

CRAWFORD, HM ;

LUMPKIN, M ;

MCDONALD, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (16) :4087-4088

[9]

CRAWFORD HM, 1941, J AM CHEM SOC, V63, P1070

[10]

CRAWFORD HM, 1939, J AM CHEM SOC, V61, P3310

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