SYNTHESIS AND CHARACTERIZATION OF POLYYNE PORPHYRINS

被引：30

作者：

MARUYAMA, K

KAWABATA, S

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 01期

关键词：

D O I：

10.1246/bcsj.63.170

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of conjugated polyyne porphyrins, in which two porphyrin macrocycles are connected with both ends of diarylpolyyne through aromatic ring, has been prepared and their spectroscopic behaviors were investigated. Diarylpolyyne consisting of aryl group and conjugated triple bond system have rigid and linear structure, and the two porphyrins are held at a fixed geometry and a determined distance. In their absorption spectra, porphyrin Soret bands were red- or blue-shifted depending on their edge-to-edge or face-to-face orientation.

引用

收藏

页码：170 / 175

页数：6

相关论文

共 45 条

[1] TERT-BUTYL ESTERS OF AMINO ACIDS AND PEPTIDES AND THEIR USE IN PEPTIDE SYNTHESIS [J].

ANDERSON, GW ;

CALLAHAN, FM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (13) :3359-3363

[2] RESEARCHES ON ACETYLENIC COMPOUNDS .41. THE SYNTHESIS OF DIPHENYLPOLYACETYLENES [J].

ARMITAGE, JB ;

ENTWISTLE, N ;

JONES, ERH ;

WHITING, MC .

JOURNAL OF THE CHEMICAL SOCIETY, 1954, (JAN) :147-154

[3] A BIPHENYLENEDIPORPHYRIN - 2 COFACIALLY ARRANGED PORPHYRINS WITH A BIPHENYLENE BRIDGE [J].

CHANG, CK ;

ABDALMUHDI, I .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (02) :164-165

[4] INTRAMOLECULAR LONG-DISTANCE ELECTRON-TRANSFER IN ORGANIC-MOLECULES [J].

CLOSS, GL ;

MILLER, JR .

SCIENCE, 1988, 240 (4851) :440-447

[5] DISTANCE, STEREOELECTRONIC EFFECTS, AND THE MARCUS INVERTED REGION IN INTRAMOLECULAR ELECTRON-TRANSFER IN ORGANIC RADICAL-ANIONS [J].

CLOSS, GL ;

CALCATERRA, LT ;

GREEN, NJ ;

PENFIELD, KW ;

MILLER, JR .

JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (16) :3673-3683

[6] X-RAY STRUCTURE-ANALYSIS OF A MEMBRANE-PROTEIN COMPLEX - ELECTRON-DENSITY MAP AT 3A RESOLUTION AND A MODEL OF THE CHROMOPHORES OF THE PHOTOSYNTHETIC REACTION CENTER FROM RHODOPSEUDOMONAS-VIRIDIS [J].

DEISENHOFER, J ;

EPP, O ;

MIKI, K ;

HUBER, R ;

MICHEL, H .

JOURNAL OF MOLECULAR BIOLOGY, 1984, 180 (02) :385-398

[7] LIGHT-ABSORPTION AND ENERGY-TRANSFER IN POLYENE-PORPHYRIN ESTERS [J].

DIRKS, G ;

MOORE, AL ;

MOORE, TA ;

GUST, D .

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1980, 32 (02) :277-280

[8] SYNTHESIS AND OPTICAL-PROPERTIES OF TERMINALLY SUBSTITUTED CONJUGATED POLYENES [J].

EFFENBERGER, F ;

SCHLOSSER, H ;

BAUERLE, P ;

MAIER, S ;

PORT, H ;

WOLF, HC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (02) :281-284

[9] PHOTODRIVEN ELECTRON-TRANSFER IN TRIAD MOLECULES - A 2-STEP CHARGE RECOMBINATION REACTION [J].

GUST, D ;

MOORE, TA ;

MAKINGS, LR ;

LIDDELL, PA ;

NEMETH, GA ;

MOORE, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (25) :8028-8031

[10] PHOTOINITIATED CHARGE SEPARATION IN A CAROTENOID PORPHYRIN DIQUINONE TETRAD - ENHANCED QUANTUM YIELDS VIA MULTISTEP ELECTRON TRANSFERS [J].

GUST, D ;

MOORE, TA ;

MOORE, AL ;

BARRETT, D ;

HARDING, LO ;

MAKINGS, LR ;

LIDDELL, PA ;

DESCHRYVER, FC ;

VANDERAUWERAER, M ;

BENSASSON, RV ;

ROUGEE, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (01) :321-323

← 1 2 3 4 5 →