SYNTHESIS AND CRYSTAL-STRUCTURE OF BETA-SRV2O6

被引：14

作者：

SCHNURIGER, B

ENJALBERT, R

SAVARIAULT, JM

GALY, J

机构：

[1] Centre d'Elaboration de Matériaux et d'Etudes Structurales, Laboratoire d'Optique Electronique, C.N.R.S, 29 rue Jeanne Marvig, BP 4347

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1991年 / 95卷 / 02期

关键词：

D O I：

10.1016/0022-4596(91)90120-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and growth of single crystals together with a crystal structure determination of β-SrV2O6 are reported. This high temperature form of SrV2O6 crystallizes in the orthorhombic system, space group Pnma, with a = 9.666 (1) A ̊, b = 3.6808 (4) A ̊, c = 12.529 (3) A ̊, Z = 4. The structure, determined and refined down to R = 3.1%, is described as isolated zigzag double strings with [V2O6]n composition extending along the [010] direction and built up by edge-sharing VO6 octahedra. Strontium atoms occupy tricapped trigonal prisms of oxygen atoms pertaining to three different strings and assume the stability of the network. © 1991.

引用

页码：397 / 402

页数：6

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