ORTHORHOMBIC CRYSTAL FORM OF TRANS-CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)RHODIUM(I) DICHLOROMETHANE SOLVATE

被引：18

作者：

CHALONER, PA ^{[1
]}

CLAVER, C ^{[1
]}

HITCHCOCK, PB ^{[1
]}

MASDEU, AM ^{[1
]}

RUIZ, A ^{[1
]}

机构：

[1] FAC QUIM TARRAGONA,DEPT QUIM,E-43005 TARRAGONA,SPAIN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270190013804

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[RhCl(C18H15P)2(CO)].CH2Cl2, M(r) = 775.9, orthorhombic, Pbca, a = 23.345 (3), b = 20.644 (7), c = 7.965 (3) angstrom, V V 3821.9 angstrom 3, Z = 4, D(x) = 1.35 g cm-3, monochromated Mo K-alpha radiation, lambda = 0.71069 angstrom, mu = 7.6 cm-1, F(000) = 1576, T = 298 K, R = 0.056 and wR = 0.063 for 587 observed reflections with \F2\ > 3-sigma(F2). The geometry at Rh is close to square planar and bond lengths and angles are similar to those in the previous determinations of the unsolvated structure.

引用

页码：1307 / 1308

页数：2

共 4 条

[1] THE CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I) IN ITS MONOCLINIC FORM [J].