The Vibrational Spectrum and Structure of the Difluorochlorinium(III) Cation, ClF2+

被引：46

作者：

Gillespie, R. J. ^{[1
]}

Morton, M. J. ^{[1
]}

机构：

[1] McMaster Univ, Dept Chem, Hamilton, ON, Canada

来源：

INORGANIC CHEMISTRY | 1970年 / 9卷 / 03期

关键词：

D O I：

10.1021/ic50085a036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Raman spectra of the compounds ClF2 center dot SbF6, ClF2 center dot AsF6, and ClF2 center dot BF4 have been measured. The fundamental frequencies of the ClF2+ ion have been reassigned and force constants calculated. It is confirmed that ClF2+ is bent and it is concluded that there is fluorine bridging between the ClF2+ ion and the anions.

引用

页码：616 / 618

页数：3

共 8 条

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