A ROUTE TO CHIRAL EPOXYPYRROLOINDOLES VIA OXIRANYL RADICAL CYCLIZATION

被引：20

作者：

ZIEGLER, FE

HARRAN, PG

机构：

[1] Sterling Chemistry Laboratory Yale University New Haven

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 28期

关键词：

D O I：

10.1016/0040-4039(93)88070-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An oxiranyl radical has been generated from a glycidic acid via the thiohydroxamic acid anhydride route. The radical has been shown to undergo cyclization, a process, which to our knowledge, has not been reported previously. The structure and the reactivity of the indole and dihydroindole products of the cyclization are discussed.

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页码：4505 / 4508

页数：4

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