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FURTHER EVIDENCE FOR THE FE-II-FE-IV AND FE-III-FE-V MANIFOLDS IN THE SUBSTITUTION OF SATURATED-HYDROCARBONS

被引：22
作者：
BARTON, DHR
CHABOT, BM
DELANGHE, NC
HU, B
LEGLOAHEC, VN
WAHL, RUR
机构：
[1] Department of Chemistry, Texas A and M University, College Station
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 39期
关键词：
D O I：
10.1016/0040-4039(95)01450-V
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The substitution of saturated hydrocarbons by the anions nitrite, thiocyanate, azide and chloride, using H2O2 and TBHP as oxidants has been shown to depend upon the Fe-II-Fe-IV manifold and to involve radical chemistry. As soon as the Fell has been oxidised to Fe-III, the reactions proceed in the Fe-III-F-V manifold where oxidation, but no anion substitution, is seen.
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页码：7007 / 7010
页数：4
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