STEAM CRACKING OF HYDROCARBONS .2. PYROLYSIS OF METHYLCYCLOHEXANE

被引：24

作者：

BAJUS, M

VESELY, V

LECLERCQ, PA

RIJKS, JA

机构：

[1] EINDHOVEN UNIV TECHNOL, INSTRUMENTAL ANAL LAB, EINDHOVEN, NETHERLANDS

[2] SLOVAK UNIV TECHNOL BRATISLAVA, DEPT CHEM & TECHNOL PETR, CS-88037 BRATISLAVA, CZECHOSLOVAKIA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT | 1979年 / 18卷 / 02期

关键词：

D O I：

10.1021/i360070a012

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The thermal decomposition of methylcyclohexane in the presence of steam was studied in a laboratory tubular reactor with large inner surface at atmospheric pressure. Experimental data were obtained at a temperature range of 700-790 °C and at residence times of 0.04-0.20 s. The overall kinetic analysis gives a value of 201.3 kJ mol-1 for the activation energy and 0.532 X 1011 s_1 for the frequency factor. The pyrolysis products (more than 90) were identified with capillary gas chromatography by comparison of their retention indices with those of standard hydrocarbons and by mass spectrometry. © 1979, American Chemical Society. All rights reserved.

引用

页码：135 / 142

页数：8

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