Rate of recombination of trichloromethyl radicals in the gas phase

被引：14

作者：

De Mare, G. R. ^{[1
]}

Huybrechts, G. H. ^{[1
]}

机构：

[1] Univ Libre Bruxelles, Serv Chim, Brussels, Belgium

来源：

CHEMICAL PHYSICS LETTERS | 1967年 / 1卷 / 02期

关键词：

D O I：

10.1016/0009-2614(67)80071-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rate constant for the recombination of trichloromethyl radicals has been measured in the gas-phase photochlorination of chloroform at 344.7 degrees K. The observed value is 10(9.62) mole(-1) l sec(-1), much lower than the value credicted by transition state calculations using Gorin's model.

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页码：64 / 65

页数：2

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