THE TRANSFER-COEFFICIENT IN PROTON-TRANSFER REACTIONS

被引：14

作者：

SCHMICKLER, W ^{[1
]}

机构：

[1] UNIV BONN,INST PHYS CHEM,W-5300 BONN,GERMANY

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 284卷 / 02期

关键词：

D O I：

10.1016/0022-0728(90)85037-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The temperature dependence of the transfer coefficient observed in proton transfer reactions is discussed. In contrast to electron transfer reactions, the electric field is expected to have a major effect on the potential energy surfaces of the system. This idea is incorporated into the quantum theory of electrochemical proton transfer reactions, and shown to give rise to temperature dependent transfer coefficients. © 1990.

引用

页码：269 / 277

页数：9

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