STRUCTURE OF MATRIX-ISOLATED S-CIS-1,3-BUTADIENE FROM POLARIZED IR-SPECTRA - A CLOSER LOOK

被引：64

作者：

ARNOLD, BR ^{[1
]}

BALAJI, V ^{[1
]}

MICHL, J ^{[1
]}

机构：

[1] UNIV TEXAS,CTR STRUCT & REACTIV,DEPT CHEM,AUSTIN,TX 78712

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1990年 / 112卷 / 05期

关键词：

D O I：

10.1021/ja00161a025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A re-examination of polarized IR spectra of the minor conformer of 1,3-butadiene isolated in argon matrix and partially aligned by photoselection confirms the previous conclusion that in weakly interacting solid environments this species is planar, i.e., s-cis, and not gauche as often believed. © 1990, American Chemical Society. All rights reserved.

引用

页码：1808 / 1812

页数：5

共 31 条

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