IMPROVED SYNTHESES AND STRUCTURE OF [(MN(III)MN(IV)(O)(2)(PHEN)(4)](CLO4)(3)CENTER-DOT-2CH3COOH-CENTER-DOT-2H2O

被引：40

作者：

MANCHANDA, R ^{[1
]}

BRUDVIG, GW ^{[1
]}

DEGALA, S ^{[1
]}

CRABTREE, RH ^{[1
]}

机构：

[1] YALE UNIV, DEPT CHEM, NEW HAVEN, CT 06511 USA

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 22期

关键词：

D O I：

10.1021/ic00100a049

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We present two new-routes to synthesize [(MnMnIV)-Mn-III(O)(2)(phen)(4)](ClO4)(3) (1, phen = 1,10-phenanthroline). The crystal structure of 1 shows structurally distinct Mn ions with a Jahn-Teller distorted Mn-III and an undistorted Mn-IV, indicating an electron-localized complex; the 16-line EPR signal from 1 also shows that this is a trapped-valences complex.

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页码：5157 / 5160

页数：4

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