PROOF OF A THEOREM ON DETERMINANCY OF PHENOMENOLOGICAL COEFFICIENTS FOR DEPENDENT FLUXES

被引：4

作者：

BARTELT, JL

HORNE, FH

机构：

[1] Department of Chemistry, Michigan State University, East Lansing

[2] Bell Telephone Laboratories, Inc., Murray Hill, NJ

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 01期

关键词：

D O I：

10.1063/1.1671709

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Although it is often convenient in both microscopic and macroscopic transport theories to use dependent fluxes, the extra phenomenological coefficients introduced thereby are apparently indeterminate unless mechanical equilibrium or the Onsager reciprocal relations are invoked. A simple proof based on entropy production verifies that the extra coefficients are generally determinate.

引用

页码：210 / &

共 12 条

[1] MACROSCOPIC APPROACH TO RECIPROCAL RELATIONS IN IRREVERSIBLE THERMODYNAMICS [J].