ELECTRON-SPIN RESONANCE STUDY OF MANGANESE(II) IONS IN TRIGONAL-PRISMATIC COORDINATION IN TRIS-(ACETYLACETONATO)METAL(II) ANIONS

被引：15

作者：

BIRDY, RB ^{[1
]}

GOODGAME, M ^{[1
]}

机构：

[1] UNIV LONDON,IMPERIAL COLL SCI & TECHNOL,INORGAN CHEM RES LABS,LONDON SW7 2AY,ENGLAND

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 02期

关键词：

D O I：

10.1021/ic50192a060

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

ESR spectra are reported for manganese(II) ions doped into polycrystalline MI[MII(acac)3] nH2O (M1=Na, K; M11=Co, Ni, Zn, Cd). Zero-field splitting parameters D andλ (=E/D) are derived, and the results are correlated with the distortions of the anions from octahedral geometry. For the cadmium compounds, the high values of D are consistent with trigonal-prismatic geometry, for K[M(acac)3] (M=Co, Ni) the results indicate near-octahedral structures, while for Na[M(acac)3] nH2O (M=Co, Ni, Zn) intermediate values are obtained. © 1979, American Chemical Society. All rights reserved.

引用

页码：472 / 475

页数：4

共 16 条

[1] ELECTRON-SPIN RESONANCE STUDY OF MANGANESE(II) DOPED INTO HEXAKIS-(4-METHYLPYRIDINE N-OXIDE)-ZINC, CADMIUM, AND MERCURY PERCHLORATES [J].

BIRDY, RB ;

GOODGAME, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (05) :461-463

[2] ZERO-FIELD SPLITTING CALCULATIONS .1. EVALUATION OF POSSIBLE PERTURBATION MECHANISMS FOR MN-2+ ION IN AN AXIAL CRYSTALLINE ELECTRIC-FIELD [J].

CHATTERJEE, R ;

SMITH, MR ;

BUCKMASTER, HA .

CANADIAN JOURNAL OF PHYSICS, 1976, 54 (12) :1224-1227

[3] DETERMINATION OF STEREOCHEMISTRY OF MANGANESE(2) COMPLEXES BY ELECTRON SPIN RESONANCE [J].

DOWSING, RD ;

GIBSON, JF ;

GOODGAME, DM ;

GOODGAME, M ;

HAYWARD, PJ .

NATURE, 1968, 219 (5158) :1037-&

[4]

DWYER FP, 1956, J P ROY SOC NS WALES, V90, P29

[5]

GIBSON JB, UNPUBLISHED

[6] HYDRATED COMPLEXES OF MANGANESE(II) AND COBALT(II) HALIDES WITH HETEROCYCLIC LIGANDS [J].

GOODGAME, M ;

HAYWARD, PJ .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (21) :3406-&

[7] CRYSTAL-STRUCTURE OF POTASSIUM TRIS(ACETYLACETONATO)CADMATE(II) MONOHYDRATE [J].

GREANEY, TM ;

RASTON, CL ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (10) :876-879

[8] TRIGONAL LIGAND-FIELD AND ZERO-FIELD SPLITTING DIAGRAMS FOR D-5 CONFIGURATION [J].

HEMPEL, JC .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (11) :4307-4313

[9] BICAPPED TETRAHEDRAL, TRIGONAL PRISMATIC, AND OCTAHEDRAL ALTERNATIVES IN MAIN AND TRANSITION GROUP 6 COORDINATION [J].

HOFFMANN, R ;

HOWELL, JM ;

ROSSI, AR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (09) :2484-2492

[10] Equivalent chemical bonds formed by s, p, and d eigenfunctions [J].

Hultgren, R .

PHYSICAL REVIEW, 1932, 40 (06) :0891-0907

← 1 2 →