NEW HETERODIFUNCTIONAL LIGANDS FOR ORGANOTRANSITON-METAL CHEMISTRY - PH2P(CH2)NC5ME4H, PH2P(CH2)2C5ME4H

被引:54
作者
SZYMONIAK, J
BESANCON, J
DORMOND, A
MOISE, C
机构
[1] Laboratoire de Synthese et d'Electrosynthese Organometalliques associe au CNRS (URA 33), Faculte des Sciences Gabriel
关键词
D O I
10.1021/jo00292a011
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of two new heterodifunctional ligands for organotransition-metal chemistry, Ph2P(CH2)nC5Me4H (n = 0, 2), is described. Both compounds are derived from the same intermediate, lithium tetramethylcyclo-pentadienide. For n = 2 the ligand is obtained by a one-pot reaction including two successive nucleophilic substitutions. © 1990, American Chemical Society. All rights reserved.
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页码:1429 / 1432
页数:4
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