USE OF 2,2'-BIPHOSPHININES FOR THE STABILIZATION OF REDUCED TRANSITION-METAL SPECIES - ELECTROCHEMICAL REDUCTION OF BIS (2,2'-BIPHOSPHININE)NICKEL(0)

被引：36

作者：

LEFLOCH, P

RICARD, L

MATHEY, F

JUTAND, A

AMATORE, C

机构：

[1] ECOLE POLYTECH,DCPH,HETEROATOMES & COORDINAT LAB,CNRS,URA 1499,F-91128 PALAISEAU,FRANCE

[2] ECOLE NORMALE SUPER,DEPT CHIM,CNRS,URA 1679,F-75231 PARIS 05,FRANCE

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 01期

关键词：

D O I：

10.1021/ic00105a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and the X-ray crystal structure of a bis(biphosphinine)nickel (0) complex are described. An electrochemical study of the reduction of this complex demonstrates that the biphosphinine acts as a more efficient ligand for the stabilization of electron excessive metal centers than bipyridine.

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页码：11 / 12

页数：2

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