STUDIES USING RADIOISOTOPES .6. HYDROGEN ISOTOPE EXCHANGE IN AROMATIC-COMPOUNDS IN THE PRESENCE OF RANEY-NICKEL ALLOY

被引：8

作者：

FINLAYSON, AC ^{[1
]}

KRISHNA, R ^{[1
]}

KALLURY, MR ^{[1
]}

PRAGER, RH ^{[1
]}

机构：

[1] UNIV ADELAIDE,DEPT ORGAN CHEM,ADELAIDE 5001,S AUSTRALIA,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1071/CH9790189

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aromatics undergo rapid proton-deuterium or -tritium exchange in aqueous solutions containing Raney nickel alloy. The specificity of exchange in benzoic acid, anthranilic acid, pyridine and aniline is investigated by degradation and mass and n.m.r. spectrometry. Positions meta and para to carboxy-late are most readily exchanged. © 1979 Australian Journal of Chemistry, All rights reserved.

引用

页码：189 / 196

页数：8

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