BASICITY OF TRANSITION-METAL CARBONYL-COMPLEXES .12. REACTIONS OF C5H5M(CO)(NO)PPH3) COMPLEXES (M=MO,W) WITH APROTIC ACIDS

被引：8

作者：

GINZBURG, AG

SETKINA, VN

KURSANOV, DN

机构：

[1] Institute of Organo-Element Compounds, USSR Academy of Sciences, Moscow, 117813

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)85884-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The aprotic acids HgCl2 and SnCl4 react with the complexes C5H5Mo(CO)(NO)(PPh3) (M Mo, W) by electrophilic attack at the transition metal centre. In the case of SnCl4 the initial reaction is followed by elimination of Cl-. This reaction can be viewed as a SN displacement of chloride by the transition metal centre. © 1979.

引用

页码：C1 / C4

页数：4

共 14 条

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