JAHN-TELLER, PSEUDO JAHN-TELLER COUPLING, AND CIRCULAR-DICHROISM SPECTRA OF (E+A) STAR-E SYSTEMS

被引:56
作者
ZGIERSKI, MZ [1 ]
PAWLIKOWSKI, M [1 ]
机构
[1] POLISH ACAD SCI,SURFACE CHEM & CATALYSIS RES LABS,PL-30060 CRACOW,POLAND
关键词
D O I
10.1063/1.437879
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The vibronic coupling problem in a (E + A)*e system of molecular levels is analyzed. Both Jahn-Teller and pseudo Jahn-Teller interactions are taken into account. The Jahn-Teller interaction is assumed to be linear and/or quadratic, whereas the pseudo Jahn-Teller interaction is taken linear in the doubly degenerate nuclear coordinate. Systems of vibronic levels are discussed for different sets of vibronic coupling parameters and energy gaps, and corresponding chiro-optical spectra are presented. © 1979 American Institute of Physics.
引用
收藏
页码:3444 / 3452
页数:9
相关论文
共 19 条
[1]   NATURAL OPTICAL-ACTIVITY OF CO(EN)33+ AND CR(EN)33+ - INTERPRETATIONS WITH COMPLETE OPERATOR MATRICES [J].
EVANS, RS ;
SCHREINE.AF ;
HAUSER, PJ .
INORGANIC CHEMISTRY, 1974, 13 (09) :2185-2192
[2]  
Griffith JS., 1961, THEORY TRANSITION ME
[3]   OPTICAL-ROTATORY STRENGTH OF TRIS-BIDENTATE COBALT(III) COMPLEXES [J].
JUDKINS, RR ;
ROYER, DJ .
INORGANIC CHEMISTRY, 1974, 13 (04) :945-950
[4]   OPTICAL ACTIVITY OF COORDINATION COMPOUNDS .2. MOLECULAR ORBITAL MODEL + ANALYSIS OF EXPERIMENTAL DATA FOR COMPLEXES OF TRIGONAL SYMMETRY [J].
KARIPIDES, AG ;
PIPER, TS .
JOURNAL OF CHEMICAL PHYSICS, 1964, 40 (03) :674-&
[5]  
KUHN W, 1938, NATURWISSENSCHAFTEN, V19, P289
[7]  
Longuet-Higgins H. C., 1961, ADV SPECTROSC, V2, P429
[8]  
LONGUETHIGGINS HC, 1958, P ROY SOC LOND A MAT, V224, P1
[9]   OPTICAL ROTATORY POWER OF CO-ORDINATION COMPOUNDS .15. REGIONAL RULES AND ELECTRONIC MECHANISMS FOR OPTICAL ACTIVITY OF D-]D TRANSITIONS [J].
MASON, SF .
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (04) :667-&
[10]   VIBRONIC STATES OF OCTAHEDRAL COMPLEXES [J].
MOFFITT, W ;
THORSON, W .
PHYSICAL REVIEW, 1957, 108 (05) :1251-1255