Mossbauer study of IF6+AsF6- and Cs+IF6-: structure and nature of the bond

被引：15

作者：

Bukshpan, S. ^{[1
]}

Soriano, J. ^{[1
]}

Shamir, J. ^{[2
]}

机构：

[1] Soreq Nucl Res Ctr, IL-70600 Yavne, Israel

[2] Hebrew Univ Jerusalem, Dept Inorgan & Analyt Chem, IL-91904 Jerusalem, Israel

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 4卷 / 05期

关键词：

D O I：

10.1016/0009-2614(69)80173-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Mossbauer effect in I-129 was used to investigate the structure of IF6+AsF6-, and Cs+IF6- complexes. The symmetry of the IF6+ ion was found to he octahedral in agreement with other measurements. A possible structure of the IF6- ion is presented. The limiting values of ionicity of the I - F bond have been calculated.

引用

页码：241 / 242

页数：2

共 6 条

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[2] MOSSBAUER INVESTIGATION OF FROZEN SOLUTIONS OF 129I2
BUKSHPAN, S
GOLDSTEIN, C
SONNINO, T
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (12) : 5477 - +
[3] BUKSHPAN S, IN PRESS J CHEM PHYS
[4] INFRARED AND RAMAN SPECTRA OF HEXAFLUOROIODINE(V) ANION IF6-
CHRISTE, KO
GUERTIN, JP
SAWODNY, W
[J]. INORGANIC CHEMISTRY, 1968, 7 (03) : 626 - &
[5] HEXAFLUOROIODINE(7) CATION IF6+
CHRISTE, KO
SAWODNY, W
[J]. INORGANIC CHEMISTRY, 1967, 6 (10) : 1783 - &
[6] PASTERNAK M, 1968, J CHEM PHYS, V48, P1967

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