STEADY-STATE OF A BISMUTH-TIN CATALYST IN THE OXIDATIVE DEHYDRODIMERIZATION OF PROPYLENE

被引：10

作者：

MAMEDOV, EA ^{[1
]}

GAMIDZADE, EG ^{[1
]}

PANKRATIEV, YD ^{[1
]}

KULIEV, AR ^{[1
]}

RIZAEV, RG ^{[1
]}

机构：

[1] ACAD SCI USSR,INST CATALYSIS,NOVOSIBIRSK 90,USSR

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1979年 / 10卷 / 01期

关键词：

D O I：

10.1007/BF02067506

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of the extent of reduction of a bismuth-tin oxide catalyst on the rate of oxidative dehydrodimerization and total oxidation of propylene and on the oxygen binding energy has been studied by pulse and calorimetric techniques. It is shown that the steady state surface is reduced by 80% and is characterized by the presence of one type of oxygen with a binding energy of 90 kcal/mol. © 1979 Akadémiai Kiadó.

引用

页码：19 / 23

页数：5

共 6 条

[1] DEPENDENCE OF CATALYTIC PROPERTIES OF COBALT MOLYBDATE IN PROPYLENE OXIDATION ON SURFACE REDUCTION AND OXYGEN BOND-ENERGY [J].

ANDRUSHKEVICH, TV ;

BORESKOV, GK ;

PANKRATIEV, YD ;

POPOVA, GY ;

KOZMENKO, ON ;

KULIEV, AR .

REACTION KINETICS AND CATALYSIS LETTERS, 1977, 7 (02) :187-191

[2] INTERACTION BETWEEN COMPONENTS OF REACTION MIXTURE AND SURFACE OF CATALYSTS FOR OXIDATIVE AMMONOLYSIS OF PROPYLENE [J].

BARANNIK, GB ;

VENYAMINOV, SA ;

BORESKOV, GK ;

WOLF, H .

REACTION KINETICS AND CATALYSIS LETTERS, 1975, 2 (03) :191-197

[3]

Boreskov G.K., 1975, KINET KATAL, V16, P1442

[4]

MAMEDOV EA, 1977, KINET KATAL, V18, P814

[5]

PANKRATE.YD, 1969, DOKL AKAD NAUK SSSR+, V184, P611

[6]

SCHUKIN VP, 1971, KINET KATAL, V12, P621

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