MANGANESE FISCHER CARBENE CHEMISTRY - REACTIONS OF CP'(CO)2MN=C(OME/OLI)R WITH ENYNES, 1-HEXYNE, AND ACRYLATES

被引：25

作者：

HOYE, TR

REHBERG, GM

机构：

[1] Department of Chemistry, University of Minnesota, Minneapolis

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 12期

关键词：

D O I：

10.1021/om00162a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of the title carbene complexes, both the neutral methoxy (1a,b) and anionic “lithoxy” (1c) versions, with α,ω-enynes 2 give the bicyclic cyclopropanes 3. The anion also reacts with 1-hexyne to give the butenolide 5 and with acrylate esters to give the γ-keto esters 8. © 1990, American Chemical Society. All rights reserved.

引用

页码：3014 / 3015

页数：2

共 7 条

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[2] UBERGANGSMETALL-CARBEN-KOMPLEXE .2. PHENYLMETHOXYCARBEN- UND METHYLMETHOXYCARBEN-PENTACARBONYLCHROM -MOLYBDAN -WOLFRAM UND -CYCLOPENTADIENYL-DICARBONYL-MANGAN
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MAASBOL, A
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[3] (1-OXIDOALKYLIDENE)PENTACARBONYLCHROMIUM ANION [R(O-)C=CR(CO)5]-[--] ACYLPENTACARBONYLCHROMATE [ACYL-CR-(CO)5] CHEMISTRY - INSITU PREPARATION AND REACTIONS WITH ALKYNES AND ENYNES
HOYE, TR
REHBERG, GM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (07) : 2841 - 2842
[4] REACTIONS OF (CO)5CR=C(ME)N(CH2CH2)2 WITH ENYNES - MECHANISTIC INSIGHT AND SYNTHETIC VALUE OF CHANGING A CARBENE DONOR GROUP FROM ALKOXY TO DIALKYLAMINO
HOYE, TR
REHBERG, GM
[J]. ORGANOMETALLICS, 1989, 8 (08) : 2070 - 2071
[5] HOYE TR, UNPUB
[6] FISCHER CARBENE MEDIATED CONVERSIONS OF ENYNES TO BICYCLIC AND TRICYCLIC CYCLOPROPANE-CONTAINING CARBON SKELETONS
KORKOWSKI, PF
HOYE, TR
RYDBERG, DB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (08) : 2676 - 2678
[7] CONJUGATE ADDITION OF A CHIRAL MANGANESE ACETYLIDE COMPLEX TO EPOXIDES, VINYL KETONES, AND HETEROCUMULENES
LUGAN, N
KELLEY, C
TERRY, MR
GEOFFROY, GL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (08) : 3220 - 3221

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